ABSTRACT
OBJECTIVE:To study the extraction rate and speciation of antivitiligo-related elements in Opercalina turperthum by water extraction and semi-bionic extraction. METHODS:Water extraction and semi-bionic extraction were respectively used. Wa-ter-soluble state and suspension state in extract of O. turperthum were separated by microporous filtering film;organic and inorgan-ic trace elements in water-soluble state were separated by macroporous resin. The contents of Cu,Zn,Fe,Ca,Mg,Mn and Sr were detected by flame atomic adsorption spectrophotometry,and speciation analysis was conducted. RESULTS:After water extrac-tion,extraction rates of 7 trace elements were 40.47%-72.49%;ratio of suspended particles was 3.69%-8.78%;ratio of organic state/inorganic state was 104.36% in water-soluble state of Sr and 3.94%-48.39% in water-soluble state of Cu,Zn,Fe,Ca,Mg, Mn. After semi-bionic extraction,except for Mn,extraction rates of trace elements were higher than water extraction,extraction rates of Cu,Zn,Fe,Ca,Mg,Sr were 77.69%-90.19%;ratio of suspended particles was 0.39%-8.57%;the ratio of organic state/inorganic state was 72.74%-180.79% in water-soluble state of elements. CONCLUSIONS:Cu,Zn,Fe,Ca,Mg,Mn and Sr in O. turperthum are dissolved easily,mainly existing in the form of inorganic state. After semi-bionic extraction,except for Mn,the dis-solution rate of other elements and the proportion of organic trace elements after dissolution increase significantly. Both dissolution and effective utilization rate of trace elements by semi-bionic extraction are higher than water extraction.
ABSTRACT
Objective:To determine the content of copper and zinc in tea by flame atomic absorption spectrophotometry and to investigate the influence on the content after leached for different time. Methods:The tea samples were leached for different time by boiling water and then the content of copper and zinc was determinated by flame atomic absorption spectrophotometry. Results:When the leaching time was less than 10 min, the content of copper and zinc increased significantly with the prolongation of the leaching time, while the increase was not obvious when the leaching time was more than 10 min. Copper and zinc showed good linearity in the range of 0.02-0.15 mg/L and 0.05-0.30 mg/L,separately. The recovery was in the range of 98.5%-101.1%for copper and 98.7%-101.2%for zinc with the RSD of 0.8%in copper and zinc (n=9) . Conclusion:The method is suitable to determine the content of copper and zinc in tea. Leaching time can influence the content of copper and zinc in tea significantly.
ABSTRACT
Cádmio foi analisado por espectrofotometria de absorção atômica com chama em 161 amostras de peixe e de outras espécies marinhas comumente consumi das e encontradas em três pontos do litoral brasileiro: Estuário de Santos, no Estado de São Paulo, Baía da Guanabara, no Estado do Rio de Janeiro, e Baía de Todos os Santos, no Estado da Bahía. De todas as amostras analisadas, 90% apresentaram teor de cádmio abaixo de 0,03 mg/kg, sendo que na maior parte delas (85,7%) era < 0,01 mgv'kg. A mineralização da amostra foi feita por via seca. 0,01 mgv'kg. A mineralização da amostra foi feita por via seca (AU).